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By J. H. Jones

Expert Periodical stories offer systematic and specified assessment insurance of growth within the significant components of chemical examine. Written through specialists of their professional fields the sequence creates a distinct provider for the energetic learn chemist, providing usual severe in-depth bills of development specifically components of chemistry.

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Additional info for Amino Acids and Peptides (SPR Amino Acids, Peptides (RSC))vol.23

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And m . s . ) specifically located in sections preceding this one, continue to be applied in amino acids science, but are either too routine to deserve citation here, or arise in isolated, pioneering, papers; and are therefore discussed here. r. e. spectroscopy of glycine, L-alanine and B-alanine on a copper surface3e6 Amino Acids 49 have been reported. V. Resonance Raman saturation spectroscopy, a new technique concentrating on relaxation measurements with associated vibrational band resolution, has contributed a new aspect to the very substantial body of Raman data on tryptophan and its derivative^,^^^ together with data on U.

R. r. heir own right. r. studies continue to provide practical analytical support for amino acid studies, as in assignments of absolute configuration to amethyl a-amino acids through detection of the precise chemical shift for the methyl proton resonances in aqueous solutions containing the chiral lanthanoid shift c u r o ~ i u m ~ I I I ) . "The ~~ reagent resonance relative to that of its

271) Bzl (Ref. 271) Bzl 270i \ (Ref. 271) (M. ii (-)-statine Reagents: (Ref. 271) i, CH2=CMeCH2MgBr; ii, dehydration, then H2/Pd-C in CH2CI2; (Ref. 270) i, (R = H) --(R = Ac), NaBH4, allyltrimethylsilane, H2/Pd (--Prn in place of P+) Scheme 25 36 chemistry Amino Acids and Peptides through the same intermediate has been demonstratrd, 272 Diastereoselective TiClr-catalyzed allyl-metal addition to (S)-a-Bocarninoalkana1rz7" follows earlier precedent (Vol. 274 The cyclic carbamate technology that is being increasingly used (Vol.

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